http://scholars.ntou.edu.tw/handle/123456789/17736
標題: | Stable Crystalline Organic-Inorganic Hybrid Indium Phosphate with Dye Removal and Ractopamine Detection Applications | 作者: | Wang, Chu Li, Jia-Rong Li, Ying Tu, Hsiung-Lin Tzou, Der-Lii M. Wang, Chih-Min |
公開日期: | 22-四月-2021 | 出版社: | AMER CHEMICAL SOC | 卷: | 60 | 期: | 15 | 起(迄)頁: | 11655-11660 | 來源出版物: | INORGANIC CHEMISTRY | 摘要: | A highly stable framework of an organic-inorganic hybrid indium phosphate (NTOU- 7) was synthesized under hydro(solvo)thermal conditions and structurally characterized by single-crystal X-ray diffraction and solid-state NMR spectroscopy. This is the first example of a post-transition-metal phosphate incorporating tetradentate organic molecules. The In atoms in the inorganic layers are coordinated by imidazole rings of the 1,2,4,5-tetrakis(imidazol-1-ylmethyl)benzene linkers to generate a new solid-state material. NTOU-7 showed high chemical stability and displayed excellent performance for both dye removal and ractopamine (RAC) detection, which are interesting environmental and biosensing applications. The sensitivity and ultralow limit of detection were 607.9 mu A center dot mu M center dot cm(-2) and 2.74 x 10(-10) mol.L-1 (0.08 ppb), which meet the requirements stated by the Codex Alimentarius Commission (10 ppb RAC residue in beef and pork). The detection performance was confirmed by sensing spiked-in RAC in real pork samples. We also reported the synthesis, characterization, structural stability, dye removal, and sensing properties of NTOU-7. |
URI: | http://scholars.ntou.edu.tw/handle/123456789/17736 | ISSN: | 0020-1669 | DOI: | 10.1021/acs.inorgchem.1c01664 |
顯示於: | 生命科學暨生物科技學系 |
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