http://scholars.ntou.edu.tw/handle/123456789/20663
標題: | Gate-opening upon CO2 adsorption on a metal-organic framework that mimics a natural stimuli-response system | 作者: | Tseng, T. W. Lee, L. W. Luo, T. T. Chien, P. H. Liu, Y. H. Lee, S. L. Chih-Ming Wang Lu, K. L. |
關鍵字: | POROUS COORDINATION-POLYMER;CARBON-DIOXIDE CAPTURE;DRUG-DELIVERY;POTENTIAL APPLICATIONS;SINGLE-CRYSTAL;NITRIC-OXIDE;SEPARATION;LIGAND;MOF;FUNCTIONALIZATION | 公開日期: | 21-十一月-2017 | 出版社: | ROYAL SOC CHEMISTRY | 卷: | 46 | 期: | 43 | 起(迄)頁: | 14728-14732 | 來源出版物: | DALTON T | 摘要: | A dynamic metal-organic framework that consists of D-champhoratebased homochiral protuberant-grid-type networks can successively participate in gate-opening and closing processes for many cycles, which were triggered by the stimuli of the adsorption and desorption of CO2 to highly and specifically recognize CO2 over N-2 and H-2 with a high CO2 uptake of 90 mg g(-1) under 35 bar at 298 K. It is highly thermally stable and the structure remains intact at least for ten reversible gate-opening and - closing processes. Thus, it is a potential candidate for industrial CO2 capture and facile release. |
URI: | http://scholars.ntou.edu.tw/handle/123456789/20663 | ISSN: | 1477-9226 | DOI: | 10.1039/c7dt03119j |
顯示於: | 13 CLIMATE ACTION |
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