Crystal Growth and Design of Disk/Filament ZnO-Decorated 1D TiO2 Composite Ceramics for Photoexcited Device Applications

Abstract

Disk- and filament-like ZnO crystals were decorated on one-dimensional TiO2 nanostructures (TiO2-ZnO) through various integrated physical and chemical synthesis methods. The morphology of the ZnO crystals on TiO2 varied with the chemical synthesis method used. ZnO nanodisks decorated with TiO2 nanorods (TiO2-ZnO-C) were synthesized using the chemical bath deposition method, and ZnO filament-like crystals decorated with TiO2 nanorods (TiO2-ZnO-H) were synthesized through the hydrothermal method. Compared with the pristine TiO2 nanorods, the as-synthesized TiO2-ZnO composites exhibited enhanced photophysiochemical performance. Furthermore, because of their fast electron transportation and abundant surface active sites, the ZnO nanodisks in the TiO2-ZnO-C composite exhibited a higher photoactivity than those in the TiO2-ZnO-H composite. The morphology and crystal quality of the ZnO decoration layer were manipulated using different synthesis methods to realize disk- or filament-like ZnO-decorated TiO2 composites with various photoactive performance levels.