http://scholars.ntou.edu.tw/handle/123456789/22417| 標題: | Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF | 作者: | Lee, Li-Wei Kao, Ya-Chuan Chung, Mei-Ying Chang, Bor-Chen Lee, Gene-Hsiang Peng, Shie-Ming Wang, Chih-Min Liu, Yen-Hsiang Lee, Sheng-Long Lu, Kuang-Lieh |
公開日期: | 14-二月-2019 | 出版社: | ROYAL SOC CHEMISTRY | 卷: | 48 | 期: | 6 | 起(迄)頁: | 1950-1954 | 來源出版物: | DALTON TRANSACTIONS | 摘要: | An SHG-active noncentrosymmetric (3,4)-connected Zn(II)-organic framework, {[Zn-2(4-abpt)(3,4-pydc)(2)]center dot 2DMAc center dot 3MeOH center dot H2O}(n) (1-Zn), was synthesized using a mixed-ligand system. The 1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated Zn-II ions with Cu-II ions while retaining the integrity of the network. |
URI: | http://scholars.ntou.edu.tw/handle/123456789/22417 | ISSN: | 1477-9226 | DOI: | 10.1039/c8dt04472d |
| 顯示於： | 生命科學暨生物科技學系 |
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