http://scholars.ntou.edu.tw/handle/123456789/22417| Title: | Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF | Authors: | Lee, Li-Wei Kao, Ya-Chuan Chung, Mei-Ying Chang, Bor-Chen Lee, Gene-Hsiang Peng, Shie-Ming Wang, Chih-Min Liu, Yen-Hsiang Lee, Sheng-Long Lu, Kuang-Lieh |
Issue Date: | 14-Feb-2019 | Publisher: | ROYAL SOC CHEMISTRY | Journal Volume: | 48 | Journal Issue: | 6 | Start page/Pages: | 1950-1954 | Source: | DALTON TRANSACTIONS | Abstract: | An SHG-active noncentrosymmetric (3,4)-connected Zn(II)-organic framework, {[Zn-2(4-abpt)(3,4-pydc)(2)]center dot 2DMAc center dot 3MeOH center dot H2O}(n) (1-Zn), was synthesized using a mixed-ligand system. The 1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated Zn-II ions with Cu-II ions while retaining the integrity of the network. |
URI: | http://scholars.ntou.edu.tw/handle/123456789/22417 | ISSN: | 1477-9226 | DOI: | 10.1039/c8dt04472d |
| Appears in Collections: | 生命科學暨生物科技學系 |
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